es061649s_si_001.pdf (63.87 kB)
Wavelength Dependence of Fe(II) Photoformation in the Water-Soluble Fraction of Aerosols Collected in Okinawa, Japan
journal contribution
posted on 2006-12-15, 00:00 authored by Kouichirou Okada, Yukiko Kuroki, Yoshihide Nakama, Takemitsu Arakaki, Akira TanaharaWe studied photoformation of Fe(II) in the water-soluble
fractions (WSFs) of bulk aerosol particles collected in Okinawa,
Japan, using radiation at wavelengths of 313, 334, 366,
and 405 nm. Fe(II) photoformation quickly reached a steady
state within 5 min of irradiation at all wavelengths. The
steady-state Fe(II) concentrations were 85 ± 13% (n = 39)
of the total dissolved Fe (TDFe) concentrations in the
WSF solutions. Apparent quantum yields of Fe(II)
photoformation were determined based on total absorbance
of the WSF solutions, and the means (±1 S.D.) were
0.019 (±0.034), 0.021 (±0.031), 0.014 (±0.023), and 0.010
(±0.025) at 313, 334, 366, and 405 nm, respectively. Comparison
of the observed rates of Fe(II) photoformation for the
WSF solutions and the calculated rates from the known Fe(II)-forming compounds suggested that Fe(oxalate)2-
could account for the observed Fe(II) photoformation rates
if the Fe(oxalate)2- concentration is sufficiently high
(>20% of [Fe(III)]0). Furthermore, our study showed that
the calculated wavelength dependence of Fe(II) photoformation from Fe(oxalate)2- was consistent with that of Fe(II) photoformation observed in the WSF solutions. The
results obtained here have implications to daytime Fe(III)/Fe(II) cycles in the atmospheric water droplet.