Visible Light Enhanced Selective Reductive Elimination of a Methylmanganese Complex from a Heterodinuclear Dimethylphenyl(4,4′-di-tert-butyl-2,2′-bipyridine)platinum−Pentacarbonylmanganese Complex

Komiya, Sanshiro; Ezumi, Sei; Komine, Nobuyuki; Hirano, Masafumi

doi:10.1021/om900319a.s002

om900319a_si_002.pdf (212.93 kB)

Visible Light Enhanced Selective Reductive Elimination of a Methylmanganese Complex from a Heterodinuclear Dimethylphenyl(4,4′-di-tert-butyl-2,2′-bipyridine)platinum−Pentacarbonylmanganese Complex

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posted on 2009-07-13, 00:00 authored by Sanshiro Komiya, Sei Ezumi, Nobuyuki Komine, Masafumi Hirano

Novel visible light induced reductive elimination of a heterodinuclear triorganoplatinum−manganese complex, (^tBu₂bpy)Me₂PhPt−Mn(CO)₅, gives a methylmanganese complex, MnMe(CO)₅, and a methylphenylplatinum complex, PtMePh(^tBu₂bpy).

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methylmanganese Reductive Elimination Dimethylphenyl reductive elimination ComplexNovel Heterodinuclear Methylmanganese Complex PtMePh MnMe tBu 2bpy heterodinuclear Visible Light Enhanced methylphenylplatinum triorganoplatinum

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Visible Light Enhanced Selective Reductive Elimination of a Methylmanganese Complex from a Heterodinuclear Dimethylphenyl(4,4′-di-tert-butyl-2,2′-bipyridine)platinum−Pentacarbonylmanganese Complex

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