ic7b00538_si_001.pdf (913.31 kB)
Unprecedented Li+ Exchange in an Anionic Metal–Organic Framework: Significantly Enhanced Gas Uptake Capacity
journal contribution
posted on 2017-04-05, 17:25 authored by Bo Liu, Rui Zhang, Chun-Yang Pan, Hai-Long JiangWe herein report
the first example of Li+ exchanged with both the guest
H2N(Me)2+ cations located in the
channels and the coordinated metal ions from an anionic metal–organic
framework (MOF), leading to significant enhancement of the pore volume
and gas sorption abilities of the exchanged MOF. Furthermore, both
MOFs before and after Li+ exchange show good selective
adsorption for CO2 over CH4.