ao9b02768_si_001.pdf (520.08 kB)
Understanding Mechanism of Adsorption in the Decolorization of Aqueous Methyl Violet (6B) Solution by Okra Polysaccharides: Experiment and Theory
journal contribution
posted on 2019-10-18, 17:46 authored by Mengdan Wang, Qun Gu, Yanlong Luo, Danil Bukhvalov, Xiaofeng Ma, Lijun Zhu, Gefei Li, Zhenyang LuoOptimal conditions
for ultrasonic-assisted extraction of polysaccharide from Chinese
okra were found using response surface methodology. The okra polysaccharide
(OPS) was used for the adsorption of methyl violet 6B (MV). Conditions
for maximal adsorption efficiency of MV were established. The mechanism
of MV adsorption was investigated by the characterization and physicochemical
analysis of OPS before and after the adsorption of MV. Both infrared
(IR) analysis and molecular dynamics (MD) simulation suggest that
MV adsorption by OPS was an electrostatic interaction between MV and
oxygen-containing groups of OPS. Further, the results of first-principles
calculation were in agreement with IR spectroscopy measurements and
MD simulation, which were all consistent with the suggested adsorption
mechanism. Optimization of okra extraction conditions, maximized efficiency
of MV adsorption by OPS, and the understanding of the adsorption mechanism
are the highlights of this work, providing a reference for promising
applications of OPS in the treatment of wastewater in textile, paper,
and other industries.