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Two Copper-Rich Open-Framework Chalcogenides Built from Unusual [Cu5(SnxM1–x)Se10] Clusters and [(SnxM1–x)2Se6] Dimeric Linkers (M = In and Ga)

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posted on 2020-05-25, 04:46 authored by Bing Han, Jing Wang, Yong Liu, Xiang Wang, Chaozhuang Xue, Jing Lv, Zhou Wu, Rui Zhou, Dingguo Xu, Dong-Sheng Li, Tao Wu
Reported here are two unprecedented copper-rich open-framework chalcogenides constructed from unusual [Cu5(SnxM1–x)­Se10] clusters and [(SnxM1–x)2Se6] dimeric linkers (M = In and Ga). The photoresponsive properties in the IR range and the photocatalytic activity for degradation of methylene blue dye of these two isostructural semiconductors were proved to be effectively adjusted by trivalent metal ions in a cluster.

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