ic5b00934_si_003.cif (27.61 kB)
Tuning the Dimensionality of Interpenetration in a Pair of Framework-Catenation Isomers To Achieve Selective Adsorption of CO2 and Fluorescent Sensing of Metal Ions
dataset
posted on 2015-07-06, 00:00 authored by Rongming Wang, Minghui Zhang, Xiaobin Liu, Liangliang Zhang, Zixi Kang, Wen Wang, Xiaoqing Wang, Fangna Dai, Daofeng SunA pair of framework-catenation isomers
(UPC-19 and UPC-20) based on an anthracene-functionality
dicarboxylate ligand were synthesized and characterized for the first
time through tuning of the dimensionality of interpenetration. The
interpenetration dimensionality significantly influences the properties
including the porosity, gas-uptake capacity, and fluorescent sensing
ability: UPC-19 with 5-fold interpenetration is nonporous,
whereas the 3-fold interpenetration form of UPC-20 is
porous and exhibits selective adsorption of CO2 and fluorescent
sensing of Cu2+ and Fe3+ through fluorescence
quenching.