ic403121r_si_002.cif (17.13 kB)
Transmetalation of Aqueous Inorganic Clusters: A Useful Route to the Synthesis of Heterometallic Aluminum and Indium HydroxoAquo Clusters
dataset
posted on 2015-12-17, 03:22 authored by Maisha K. Kamunde-Devonish, Milton N. Jackson, Zachary L. Mensinger, Lev N. Zakharov, Darren W. Johnson[AlxIny(μ3-OH)6(μ-OH)18(H2O)24](NO3)15 hydroxy–aquo clusters
(AlxIn13–x) are synthesized through the evaporation of stoichiometrically
varied solutions of Al13 and In(NO3)3 using a transmetalation reaction. Several spectroscopic
techniques (1H NMR, 1H-diffusion ordered spectroscopy,
dynamic light scattering, and Raman) are used to compare AlxIn13–x to its Al13 counterpart. A thin film
of aluminum indium oxide was prepared from an Al7In6 cluster ink, showing its utility as a precursor
for materials.
