Total Synthesis of (+)-Lophirone H and Its Pentamethyl
Ether Utilizing an Oxonium–Prins Cyclization

Abas, Hossay; Linsdall, Sean M.; Mamboury, Mathias; Rzepa, Henry S.; Spivey, Alan C.

doi:10.1021/acs.orglett.7b00642.s001

ol7b00642_si_001.pdf (4.42 MB)

Total Synthesis of (+)-Lophirone H and Its Pentamethyl Ether Utilizing an Oxonium–Prins Cyclization

journal contribution

posted on 2017-05-05, 19:43 authored by Hossay Abas, Sean M. Linsdall, Mathias Mamboury, Henry S. Rzepa, Alan C. Spivey

The first total synthesis of (+)-lophirone H (1) and its pentamethyl ether 29, featuring an oxonium–Prins cyclization/benzylic cation trapping reaction, is described.

History

Usage metrics

Keywords

lophirone Cyclization oxonium Pentamethyl Ether Utilizing cation cyclization synthesis pentamethyl ether 29 Lophirone Total Synthesis Oxonium

Licence

CC BY-NC 4.0

Exports

RefWorks

BibTeX

Ref. manager

Endnote

DataCite

NLM

DC