Ti4(embonate)6 Based Cage-Cluster
Construction in a Stable Metal–Organic Framework for Gas Sorption
and Separation

Chen, Guang-Hui; Li, Hai-Zhen; He, Yan-Ping; Zhang, Shu-Hua; Yi, Xiaofeng; Liang, Fu-Pei; Zhang, Lei; Zhang, Jian

doi:10.1021/acs.cgd.9b01297.s001

cg9b01297_si_001.pdf (855.37 kB)

Ti₄(embonate)₆ Based Cage-Cluster Construction in a Stable Metal–Organic Framework for Gas Sorption and Separation

journal contribution

posted on 2019-12-16, 05:30 authored by Guang-Hui Chen, Hai-Zhen Li, Yan-Ping He, Shu-Hua Zhang, Xiaofeng Yi, Fu-Pei Liang, Lei Zhang, Jian Zhang

The cooperative assembly of a tetrahedral (Ti₄L₆)^8– (L = embonate) cage and a penta-nuclear [Zn₅(OH)₃(H₂O)₅]⁷⁺ cluster unit results in an unprecedented cage-cluster-based metal–organic framework that features high stability and notable selectivity toward the separation of hydrocarbons.

Ti₄(embonate)₆ Based Cage-Cluster Construction in a Stable Metal–Organic Framework for Gas Sorption and Separation

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Ti4(embonate)6 Based Cage-Cluster Construction in a Stable Metal–Organic Framework for Gas Sorption and Separation

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Ti₄(embonate)₆ Based Cage-Cluster Construction in a Stable Metal–Organic Framework for Gas Sorption and Separation