ao9b01745_si_001.pdf (1.37 MB)
Three-Dimensional-Coordination Polymer of Zn(II)-Carboxylate: Structural Elucidation, Photoelectrical Conductivity, and Biological Activity
journal contribution
posted on 2019-10-17, 14:44 authored by Angeera Chandra, Mrinmay Das, Kunal Pal, Srikanta Jana, Basudeb Dutta, Partha Pratim Ray, Kuladip Jana, Chittaranjan SinhaA newly designed mixed-ligand coordination
polymer [Zn4(bdc)4(ppmh)2(H2O)]n (1) (H2bdc =
1,4-benzene dicarboxylic acid, ppmh = N-pyridin-2-yl-N′-pyridin-4-ylmethylene-hydrazine)
has been characterized using different physicochemical techniques.
The structure has been confirmed by single crystal X-ray diffraction
measurements. There are two pyridyl-N and one hydrazino-imine-N donor
centers in ppmh, where two pyridyl-Ns bind simultaneously
to two Zn(II) to serve as a bridging agent to form a coordination
polymer. The 1,4-benzene dicarboxylato (bdc) is ligated
via the aromatic dicarboxylato-O to form a one-dimensional (1D) chain.
These two 1D chains about Zn(II) constitute a two-dimensional structure,
which undergoes noncovalent interactions (C–H···π
and π···π) to generate a three-dimensional
supramolecular assembly. Electrical conductivity of 1 is higher by 1 order (1.37 × 10–6 S/cm) than
that of the free ligand, ppmh (6.2 × 10–7 S/cm). Especially, the responsivity of the compound 1 was 56.21 mA/W, which is 11 times higher than that of the ligand ppmh (5.12 mA/W). The specific detectivity of the compound
was 2.17 × 1010 Jones, which is also almost 10 times
higher with respect to the specific detectivity of the ligand-based
device (4.53 × 109 Jones). The results show that the
compound can be valuable for optoelectronic fields. The biological
studies suggest that compound 1 is antibacterial as well
as a promising anticancer agent (LD50, 42.2 μg/mL
against HepG2 cells), while ligands remain silent. Investigation of
the mechanism of the cell killing activity of compound 1 accounts the generation of intracellular reactive oxygen species.