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Thia-Wittig-like Reactions as a New Route for the Stereoselective Synthesis of (Z)-Fluoroalkenoates
journal contribution
posted on 1999-10-17, 00:00 authored by David Chevrie, Thierry Lequeux, Jean-Claude PommeletStereoselective syntheses of (Z)-fluoroalkenoates 3a−g have been developed in three steps from the readily available fluorosulfide 5 and
aldehydes. This preparation, involving a Durst reaction, was highly stereoselective and led to fluoroalkenes in 50−60% overall yields, without
purification of intermediates.
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