The First Example of Solvothermally Synthesized Thioantimonates(V)
with Ethylenediamine Coordinated Lanthanide(III):  [Sm(en)4]SbS4·0.5en
and [Sm(en)3(H2O)(μ-SbS4)]∞

Jia, Ding-xian; Zhu, Qin-Yu; Dai, Jie; Lu, Wen; Guo, Wen-Juan

doi:10.1021/ic0484957.s001

ic0484957_si_001.pdf (36.25 kB)

The First Example of Solvothermally Synthesized Thioantimonates(V) with Ethylenediamine Coordinated Lanthanide(III): [Sm(en)₄]SbS₄·0.5en and [Sm(en)₃(H₂O)(μ-SbS₄)]_∞

journal contribution

posted on 2005-02-21, 00:00 authored by Ding-xian Jia, Qin-Yu Zhu, Jie Dai, Wen Lu, Wen-Juan Guo

Under mild solvothermal conditions two novel thioantimonates(V) [Sm(en)₄]SbS₄·0.5en (1) and [Sm(en)₃(H₂O)(μ-SbS₄)]_∞ (2) were synthesized; the structure of 1 contains discrete [Sm(en)₄]³⁺ and [SbS₄]^3- ions, while 2 consists of neutral [Sm(en)₃(H₂O) (μ-SbS₄)] one-dimensional chains.