ol400922j_si_001.cif (9.4 kB)
The Design, Synthesis and Validation of Recoverable and Readily Reusable Siloxane Transfer Agents for Pd-Catalyzed Cross-Coupling Reactions
dataset
posted on 2013-05-17, 00:00 authored by Dionicio Martinez-Solorio, Adam T. Hoye, Minh H. Nguyen, Amos B. SmithThe development of competent, recoverable and reusable 1-oxa-2-silacyclopentene
(siloxane) transfer agents for Pd-catalyzed cross-coupling reactions
(CCRs) of organolithium reagents with aryl and alkenyl iodides has
been achieved. Drawbacks of the first-generation siloxane-transfer
agent (1), relating to facile recovery for potential
recycling, have been addressed.