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Template-Free, Solid-State Synthesis of Hierarchically Macroporous S‑Doped TiO2 Nano-Photocatalysts for Efficient Water Remediation
journal contribution
posted on 2020-03-31, 19:48 authored by Vishnu
V. Pillai, Sunil P. Lonkar, Saeed M. AlhassanNanosized
sulfur-doped titanium dioxide emerged as an attractive
photocatalyst in various environmental remediation applications, yet
most synthesis methods require hazardous sulfurizing agents and intricate
synthesis procedures. Herein, we present a facile, sustainable, and
environmentally friendly preparation process for the production of
visible-light-active meso–macroporous sulfur-doped anatase
TiO2 (S-TiO2) nanoparticles for the first time.
This strategy encompasses solventless mixing of titanium salt and
surfeit yet nontoxic abundant elemental sulfur under continuous ball
milling and moderate thermoannealing. The characterizations of as-obtained
S-TiO2 nanoparticles showed enhanced physicochemical properties
including distinctive surface features composed of hierarchical hollow
macroporous channels having nanostructured mesoporous core walls.
The annealing temperature was observed to control the structure and
extent of sulfur doping in TiO2. Upon insertion of a sulfur
atom into the TiO2 lattice, the band gap energy of S-TiO2 was significantly lowered, facilitating the enhanced photochemical
activity. Owing to the effective S doping (1.7–2.8 atom %),
and the interconnected hollow meso–macroporous nanostructure,
the resulting nanosized S-TiO2 exhibited unique adsorption
properties and superior photocatalytic efficiency for the rapid degradation
of hazardous organic dyes and phenols for water remediation. The presented
strategy holds high potential to provide rapid production of a hierarchical
and highly porous S-TiO2 photocatalyst on a large scale
for various environmental remediation and other myriad photochemical
applications.