om500663m_si_005.mol (4.04 kB)
Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors
dataset
posted on 2015-12-17, 03:57 authored by Miles
W. Johnson, Antonio G. DiPasquale, Robert G. Bergman, F. Dean TosteA series of gold(III) complexes supported
by pyridine-based bis(amidate),
bis(carboxylate), and bis(iminothiolate) substituents is reported.
These compounds represent rare examples of pincer-ligated gold(III)
centers with multiple anionic heteroaom donors. Reactivity and electrochemical
studies demonstrate the stability of these compounds and the marked
difference in reduction potentials with varying ligand scaffolds.