ol0713032_si_006.pdf (2.29 MB)
Synthesis of Functionalized Pyrroles via Gold(I)-Catalyzed aza-Claisen-Type Rearrangement
journal contribution
posted on 2007-08-02, 00:00 authored by Florin M. Istrate, Fabien GagoszGold(I)-catalyzed cyclization of pentenynyl allyl tosylamides allows the rapid construction of functionalized pyrroles. The concerted aza-Claisen-type mechanism induces a complete selectivity of the process and allows the easy formation of quaternary centers.