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Synthesis of Conjugated Microporous Polymers through Cationic Cyclization Polymerization
journal contribution
posted on 2019-05-15, 12:08 authored by Hao Zhou, Bing Zhao, Cheng Fu, Ziqi Wu, Chonggang Wang, Yun Ding, Bao-Hang Han, Aiguo HuConjugated microporous polymers (CMPs)
are a kind of polymeric
materials combining both high porosities and photoelectric functions
and are applied in numerous fields. Herein, three CMPs are facilely
synthesized through cationic cyclization polymerization of monomers
with multiple enediyne moieties. The chemical structures of the CMPs
were characterized with solid-state 13C cross-polarization/magic-angle
spinning NMR spectroscopy and Fourier transform infrared spectroscopy.
The obtained CMPs exhibit high Brunauer–Emmett–Teller
specific surface areas (up to 780 m2 g–1) and excellent adsorption functionality. The highest uptake capacities
are up to 12.7 wt % for carbon dioxide (1.0 bar, 273 K) and 246 wt
% for iodine (353 K), which are superior to those of most porous organic
polymers (POPs). We believe that this metal-free strategy will provide
a novel approach toward the synthesis of CMPs and would further expand
the application scope of POPs.
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Conjugated Microporous PolymersCationic Cyclization Polymerization Conjugated microporous polymersCMPs exhibitsurface areaswtenediyne moietiesadsorption functionality273 Kmetal-free strategychemical structuresphotoelectric functionsnovel approachcationic cyclization polymerizationuptake capacitiesPOPNMR spectroscopyapplication scope
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