Synthesis of Chiral Dotriacontanaphthalenes: How Many Naphthalene Units Are We Able To Elaborately Connect?

(S,S,S,S,S,S,S,S,S,S,S,S,S,S,S,S,S,S,S,S,S,S,S,S,S,S,S,S,S,S,S)-dotriacontanaphthalenes 32AE alternately possessing butoxy and methoxy side chains were precisely constructed through a bottom-up synthesis, and their absolute configurations and fluorescence quantum yields were determined.