Synthesis and Reactivity of a Novel Class of Long-Lived Ammonium Ylides: Derivatives of Benzo[b]pyrrolo[2,1-f][1.6]naphthyridine

Name: Synthesis and Reactivity of a Novel Class of Long-Lived Ammonium Ylides: Derivatives of Benzo[b]pyrrolo[2,1-f][1.6]naphthyridine
Published: 2008-06-20T00:00:00Z
Keywords: Novel Class, pyrrolo, naphthyridine, Biochemistry, Medicine, Cell Biology, Physiology, Chemical Sciences not elsewhere classified, Information Systems not elsewhere classified, Cancer, Infectious Diseases

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Synthesis and Reactivity of a Novel Class of Long-Lived Ammonium Ylides: Derivatives of Benzo[b]pyrrolo[2,1-f][1.6]naphthyridine

2008-06-20T00:00:00Z (GMT) by Leonid G. Voskressensky Ilya V. Vorobiev Tatyana N. Borisova Alexey V. Varlamov

Reaction of 10-cyanotetrahydrobenzo[b][1,6]naphthyridines (1−6) with activated alkynes affords stable benzo[b]pyrrolo[2,1-f][1,6]naphthyridine-4-ium ylides (7−14) in moderate yields. A proposed mechanism for their formation consists of a new tandem multistage process.

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Novel Class pyrrolo naphthyridine

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