jo070318a_si_003.cif (18.66 kB)
Synthesis and Oxidation of Triarylamine Derivatives Bearing Hydrogen-Bonding Groups
dataset
posted on 2007-06-22, 00:00 authored by Hidenori Murata, Paul M. LahtiHydrogen-bonding triarylamines, 4-(N,N-bis(4-methoxyphenyl)amino)benzoic acid (TPA1), 5-(N,N-bis(4-methoxyphenyl)amino)isophthalic acid (TPA2), and N-(4-(1H-benzimidazol-2-yl)phenyl)-N,N-bis(4-methoxyphenyl)amine
(BImTPA), were synthesized as radical cation precursors.
TPA1 and TPA2 are readily p-doped by AgSbF6 to give
highly persistent radical cations. Poor solid-state spin yields
of the radical cation from BImTPA may be due to spin
delocalization.