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Synthesis and Chemistry of Bridgehead Allylsilanes. Stereoselective Reactions with Aldehydes

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journal contribution
posted on 2005-09-01, 00:00 authored by Ryan Lauchli, John M. Whitney, Liang Zhu, Kenneth J. Shea
A type II intramolecular Diels−Alder reaction provides access to bicyclo[5.3.1] ring systems with an imbedded bridgehead allylsilane. The Lewis acid catalyzed reactions of these compounds with aldehydes proceed efficiently and with control of stereochemistry.

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