ol051363c_si_001.pdf (246.64 kB)
Synthesis and Chemistry of Bridgehead Allylsilanes. Stereoselective Reactions with Aldehydes
journal contribution
posted on 2005-09-01, 00:00 authored by Ryan Lauchli, John M. Whitney, Liang Zhu, Kenneth J. SheaA type II intramolecular Diels−Alder reaction provides access to bicyclo[5.3.1] ring systems with an imbedded bridgehead allylsilane. The
Lewis acid catalyzed reactions of these compounds with aldehydes proceed efficiently and with control of stereochemistry.