ma5018296_si_001.pdf (670.92 kB)
Syntheses and Characteristics of Water-Soluble, Pyridine-Based Poly(aryleneethynylene)s
journal contribution
posted on 2014-10-28, 00:00 authored by Kai Seehafer, Markus Bender, S. Thimon Schwaebel, Uwe H. F. BunzWe have prepared a series of water-soluble,
pyridine-containing
poly(aryleneethynylene)s (PAEs), consisting of alternating units of
substituted ethynylpyridines and ethynylbenzenes. Water solubility
is achieved by branched oligoethylene glycol (swallowtail) side chains.
The fluorescence quantum yield (ϕ) of these PAEs was studied
in dependence of their structure. The emissive quantum yield is not
very dependent upon the number and position of the swallowtail substituents
as long as their number suffices to dissolve the PAE in water. Attachment
of a carboxylate group onto the pyridine unit decreases ϕ of
the PAEs. All of the PAEs were metallo-reactive. Hg2+ and
Fe3+ ions quench the fluorescence of the PAEs, while other
metal cations (Cd2+, Zn2+, Cu+, Cu2+) only quench the fluorescence of some of the PAEs. According
to the Stern–Volmer quenching constants, some of the PAEs are
more sensitive toward quenching than the well-documented dicarboxylate-PPEs.