cg9b01426_si_001.pdf (2.28 MB)
Synchrotron-Based X‑ray Analysis: Relating Compressive Lattice Strain with the Photoluminescence Intensity of Li+‑Doped β‑NaYF4:Yb3+/Ln3+ (Ln3+ = Ho3+/Er3+/Tm3+) Upconversion Crystals
journal contribution
posted on 2019-12-15, 15:13 authored by Preeti Verma, Debasish Sarkar, Parasmani Rajput, Manvendra Narayan Singh, Rajendra Sharma, Supratim GiriThe highly intense synchrotron-radiation-based X-ray
beams offer
an undisputed advantage in assessing the structural parameters of
crystalline solids. Herein, through extensive synchrotron-based probing,
an attempt was made to understand the structural attributes that dictate
the variation of upconversion luminescence intensity (UCL) resulting
from the distortion of local crystal field symmetry. Four different
sets of UC crystals (NaYF4/Yb3+/Ln3+: Ln = Ho, Er, Tm) have been designed with varying Li+ concentrations. The analysis indicated that, out of many possible
structural factors, the compressive lattice strains generated in those
systems exhibited an unexpected correlation with the respective UCL
intensities near their maximum values, irrespective of the activator
species. Interestingly, the single-activator-based samples showed
maximum UCL intensities when their respective compressive lattice
strains reached close to a particular value. Through experimental
evidence, these findings tend to extend and complement the existing
hypothesis of symmetry distortion of a UC lattice by chemical manipulation.