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Sustainable Transesterification of Cellulose with High Oleic Sunflower Oil in a DBU-CO2 Switchable Solvent
journal contribution
posted on 2018-05-21, 00:00 authored by Kelechukwu
N. Onwukamike, Stéphane Grelier, Etienne Grau, Henri Cramail, Michael A. R. MeierThe
direct transesterification of cellulose with high oleic sunflower
oil, without any activating steps, was achieved in a DBU-CO2 solvent system to obtain fatty acid cellulose esters (FACEs). Optimization
of the reaction parameters (i.e., concentration, temperature, plant
oil equivalents, as well as reaction time) was performed using microcrystalline
cellulose (MCC) and followed by Fourier-transform infrared spectroscopy
(FT-IR). Further confirmation of the FACEs structures was achieved
via 1H and 13C NMR, and 31P NMR revealed
DS (degree of substitution) values of up to 1.59. The optimized conditions
were successfully applied to filter paper (FP) and cellulose pulp
(CP). Characterization of the FACEs showed improved thermal stability
after transesterification reactions (up to 30 °C by TGA) and
a single broad 2θ peak around 19.8° by XRD, which is characteristic
of a more amorphous material. In addition, films were prepared via
solvent casting and their mechanical properties obtained from tensile
strength measurements, revealing an elastic modulus (E) of up to 478 MPa with elongation of about 35% and a maximum stress
of 22 MPa. The film morphology was studied by scanning electron microscopy
(SEM) and showed homogeneous surfaces. In this report, we thus demonstrated
a more sustainable approach toward FACEs that combines cellulose and
plant oil (two renewable resources) directly, resulting in fully renewable
polymeric materials with appealing properties.
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13 C NMRSustainable Transesterification31 P NMRFACEs structuresacid cellulose estersFT-IR22 MPafilter paper2θ peakreaction time478 MPamaterialstrength measurementsHigh Oleic Sunflower OilXRDtransesterification reactionsoptimized conditionsFPfilm morphologymicrocrystalline cellulosereaction parametersSEM1 Hscanning electron microscopyCPDBU-CO 2oleic sunflower oilDScellulose pulpTGAplant oil equivalentsplant oilDBU-CO 2 Switchable SolventMCC
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