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Suspensions of Semiconducting Nanoparticles in Nafion for Transient Spectroscopy and Terahertz Photoconductivity Measurements
journal contribution
posted on 2020-03-05, 18:05 authored by Jacob
A. Spies, Miryl J. Hilibrand, Jens Neu, Sarah Ostresh, John R. Swierk, Charles A. SchmuttenmaerThe characterization of emerging
materials is crucial for the experimentally
driven design of next-generation technologies. We describe a cost-
and time-effective method for suspending nanoparticles and other photoactive
materials in Nafion for transient spectroscopy and time-resolved terahertz
(THz) photoconductivity measurements. Nafion is an ideal suspension
matrix because it has high transparency throughout the UV/vis/near-IR
and THz regions of the spectrum. Suspensions of nanoparticles in Nafion
require only small amounts of sample (<5 mg) and can be prepared
and deposited in ∼1 h. The suspension is well-suited for transient
THz measurements, which can be used to determine the photoconductivity
spectrum of the embedded nanoparticles. In this work, we used silicon
nanoparticles as a model material to demonstrate the efficacy of Nafion
suspensions for transient THz spectroscopy. This methodology can be
used for rapid and cost-effective measurements of emerging materials
such as solar materials, electrocatalysts, and nanomaterials.
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photoactive materialssilicon nanoparticlesTHz measurementsTransient SpectroscopySuspensiontime-effective methodphotoconductivity spectrumphotoconductivity measurementssuspension matrixmodel materialTHz spectroscopySemiconducting NanoparticlesTHz regionsTerahertz Photoconductivity Measurementstime-resolved terahertzUVNafion suspensionsnext-generation technologies
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