om200878e_si_005.cif (23.23 kB)
Subtle Reactivities of Boron and Aluminum Complexes with Amino-Linked N-Heterocyclic Carbene Ligation
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posted on 2012-01-23, 00:00 authored by Chia-Cheng Tai, Ya-Ting Chang, Jie-Hong Tsai, Titel Jurca, Glenn P. A. Yap, Tiow-Gan OngThis paper describes the synthesis and characterization
of trimethylaluminum (2a), dimethylaluminum (3a), and triphenylboron complexes (7) supported by functional
amine-linked NHC ligands. The chemical reactivity studies with carbodiimide
and isocyanate were preformed with 2a and 3a, illustrating the noninnocent nature in Al–carbene bonding.
However, the boron–carbene interaction is quite robust against
addition of these substrates even at higher temperature conditions.
The subtle difference in chemical reactivity between aluminum and
boron is attributed from the metal–carbene bond covalency.
Development of the catalytic method for Suzuki–Miyaura coupling
utilizing triphenylboron reagent supported by amino-NHC is also presented.
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Keywords
carbodiimidecharacterizationLigationThipreformedSuzukiligandNHCtriphenylboron reagenttemperature conditionsmethodcomplexCarbenesynthesisAluminum ComplexescovalencySubtle Reactivitieschemical reactivitytrimethylaluminumBoronisocyanateinteractionsubstratechemical reactivity studiesnoninnocent naturebonddimethylaluminum
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