ma300775b_si_001.pdf (837.67 kB)
Structure–Conductivity Relationship for Peptoid-Based PEO–Mimetic Polymer Electrolytes
journal contribution
posted on 2016-02-20, 18:38 authored by Jing Sun, Gregory
M. Stone, Nitash P. Balsara, Ronald N. ZuckermannPolymer electrolytes offer great potential for application
in lithium
batteries. In order to systematically optimize the performance of
these materials, atomic level synthetic control over the polymer chemical
structure is desired. In this study, we designed a series of chemically
defined, monodisperse peptoid polymers to explore the impact of side-chain
structure on the thermal and electrical properties. A series of comblike
peptoid homopolymers with ethylene oxide (EO)n side chains of varying length were synthesized by a rapid
solid phase synthetic method. The electrical properties of these materials
with dissolved lithium salt were characterized by ac impedance. The
temperature dependence of the ionic conductivity of the polypeptoid
electrolytes is consistent with the Vogel–Tamman–Fulcher
equation. The optimum ionic conductivity of 2.6 × 10–4 S/cm achieved for oligo-N-2-(2-(2-methoxyethoxy)ethoxy)ethylglycine–Li
salt complex at 100 °C, is approximately 10-fold lower than the
analogous PEO–salt complex. It is, however, nearly 2 orders
of magnitude higher than previously reported comblike PEO–mimetic
polypeptides. The ionic conductivities of these side chain analogs
vary by 3 orders of magnitude, but this variation is entirely governed
by the proximity of the system to the glass transition temperature.
This investigation shows that polypeptoids provide a unique platform
for examining the structure–property relationships of solid
polymer electrolytes.