Structural and Spectroscopic Characterization of (μ-Hydroxo or
μ-Oxo)(μ-peroxo)diiron(III) Complexes:  Models for Peroxo Intermediates of
Non-Heme Diiron Proteins

Zhang, Xi; Furutachi, Hideki; Fujinami, Shuhei; Nagatomo, Shigenori; Maeda, Yonezo; Watanabe, Yoshihito; Kitagawa, Teizo; Suzuki, Masatatsu

doi:10.1021/ja045594a.s002

ja045594a_si_002.pdf (1.34 MB)

Structural and Spectroscopic Characterization of (μ-Hydroxo or μ-Oxo)(μ-peroxo)diiron(III) Complexes: Models for Peroxo Intermediates of Non-Heme Diiron Proteins

journal contribution

posted on 2005-01-26, 00:00 authored by Xi Zhang, Hideki Furutachi, Shuhei Fujinami, Shigenori Nagatomo, Yonezo Maeda, Yoshihito Watanabe, Teizo Kitagawa, Masatatsu Suzuki

(μ-Hydroxo or oxo)(μ-1,2-peroxo)diiron(III) complexes having a tetradentate tripodal ligand (L) containing a carboxylate sidearm [Fe₂(μ-OH or μ-O)(μ-O₂)(L)₂]ⁿ⁺ were synthesized as models for peroxo-intermediates of non-heme diiron proteins and characterized by various physicochemical measurements including X-ray analysis, which provide fundamental structural and spectroscopic insights into the peroxodiiron(III) complexes.

Structural and Spectroscopic Characterization of (μ-Hydroxo or μ-Oxo)(μ-peroxo)diiron(III) Complexes: Models for Peroxo Intermediates of Non-Heme Diiron Proteins

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