ja6b09789_si_002.cif (4.71 MB)
Steric Switching from Photochemical to Thermal Reaction Pathways for Enhanced Efficiency in Metal-Mediated Nitrogen Fixation
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posted on 2016-10-25, 00:00 authored by Leila
M. Duman, Wesley S. Farrell, Peter Y. Zavalij, Lawrence R. SitaProgrammed
manipulation of the subtle interplay of nonbonded steric
interactions within a supporting ligand environment has been used
for the conversion of a photochemically driven chemical cycle for
group 6 metal-mediated nitrogen fixation into a thermally promoted
process with increased energy efficiency and atom economy for key
transformations involving NN bond cleavage and N-atom functionalization
of coordinated N2.
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ligand environmentgroup 6 metal-mediated nitrogen fixationinterplaySteric SwitchingconversionThermal Reaction Pathwaysatom economyEnhanced EfficiencytransformationPhotochemicalphotochemicallyenergy efficiencyMetal-Mediated Nitrogen Fixation Programmed manipulationN-atom functionalizationN 2cleavagenonbonded steric interactionschemical cycle
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