Stereospecific Addition of H−P Bond to
Alkenes:  A Simple Method for the
Preparation of (RP)-Phenylphosphinates

Han, Li-Biao; Zhao, Chang-Qiu

doi:10.1021/jo051582b.s001

jo051582b_si_001.pdf (587.94 kB)

Stereospecific Addition of H−P Bond to Alkenes: A Simple Method for the Preparation of (R_P)-Phenylphosphinates

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posted on 2005-11-25, 00:00 authored by Li-Biao Han, Chang-Qiu Zhao

A variety of functionalized optically pure (R_P)-alkylphenylphosphinates are readily prepared by stereospecific radical or base-catalyzed additions of the easily available (R_P)-menthyl phenylphosphinate to alkenes.

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Keywords

alkylphenylphosphinate functionalized Stereospecific Addition menthyl Alkene variety Simple Method Phenylphosphinate alkene phenylphosphinate Preparation stereospecific Bond

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Stereospecific Addition of H−P Bond to Alkenes: A Simple Method for the Preparation of (RP)-Phenylphosphinates