Stereoselective Synthesis of 2-Isocyanoallopupukeanane

1999-09-15T00:00:00Z (GMT) by Tse-Lok Ho Liang-Rern Kung
A stereoselective synthesis of 2-isocyanoallopupukeanane (3) in ca. 5% overall yield features an intramolecular Diels−Alder reaction to establish a bridged cyclopentane ring to the existing bicyclo[3.2.1]octane unit.