Stereoselective Synthesis of
2-Isocyanoallopupukeanane

Ho, Tse-Lok; Kung, Liang-Rern

doi:10.1021/ol990181d.s001

ol990181d_si_001.pdf (321.21 kB)

Stereoselective Synthesis of 2-Isocyanoallopupukeanane

journal contribution

posted on 1999-09-15, 00:00 authored by Tse-Lok Ho, Liang-Rern Kung

A stereoselective synthesis of 2-isocyanoallopupukeanane (3) in ca. 5% overall yield features an intramolecular Diels−Alder reaction to establish a bridged cyclopentane ring to the existing bicyclo[3.2.1]octane unit.

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bicyclo intramolecular Stereoselective Synthesis bridged cyclopentane ring Diel Isocyanoallopupukeanane isocyanoallopupukeanane stereoselective synthesis

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