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Solution-Dispersible Metal Nanorings with Deliberately Controllable Compositions and Architectural Parameters for Tunable Plasmonic Response

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journal contribution
posted on 12.08.2015, 00:00 by Tuncay Ozel, Michael J. Ashley, Gilles R. Bourret, Michael B. Ross, George C. Schatz, Chad A. Mirkin
We report a template-based technique for the preparation of solution-dispersible nanorings composed of Au, Ag, Pt, Ni, and Pd with control over outer diameter (60–400 nm), inner diameter (25–230 nm), and height (40 nm to a few microns). Systematic and independent control of these parameters enables fine-tuning of the three characteristic localized surface plasmon resonance modes of Au nanorings and the resulting solution-based extinction spectra from the visible to the near-infrared. This synthetic approach provides a new pathway for solution-based investigations of surfaces with negative curvature.