je0c00122_si_001.pdf (114.63 kB)
Solubility of 3,5-Dinitrosalicylic Acid in Fourteen Pure Solvents over Temperatures from 278.15 to 323.15 K
journal contribution
posted on 2020-03-27, 11:34 authored by Xi Zhao, Gui Han, Hongkun ZhaoThrough the saturation
shake-flask technique, the solubility of
3,5-dinitrosalicylic acid in 14 pure solvents such as ethylene glycol
(EG), ethanol, n-propanol, ethyl acetate, isopropanol,
acetonitrile, N,N-dimethylformamide
(DMF), N-methyl-2-pyrrolidinone (NMP), n-butanol, isobutanol, dimethyl sulfoxide (DMSO), water, cyclohexane,
and 1,4-dioxane was determined over the temperatures from 278.15 to
323.15 K at an ambient pressure of about p = 101.2
kPa. As the studied temperatures increased, the magnitude of mole
fraction solubility of 3,5-dinitrosalicylic acid in the above pure
solvents increased positively and followed the decreasing order as
NMP > DMF > DMSO > ethanol > ethyl acetate > n-propanol
> 1,4-dioxane > isopropanol > EG > isobutanol > n-butanol > acetonitrile > cyclohexane > water.
The molecule interactions
of solvent–solute and solvent–solvent were checked through
a linear solvation energy relationship. The determined solubility
was mathematically described by the Wilson model, Apelblat equation,
NRTL model, and λh equation. The obtained root-mean-square
deviation values and relative average deviation values were not greater
than 52.93 × 10–4 and 6.04 × 10–2, respectively. Also, the mixing properties, reduced excess enthalpy,
and activity coefficients at infinitesimal concentration were derived
in terms of the Wilson equation.