ol6b02578_si_003.cif (20.36 kB)
Sequential Deprotonation–Alkylation of Binaphthyloxy-Substituted Phosphonochalcogenoates: Chiral Tri- and Tetrasubstituted Carbon Centers Adjacent to a Phosphorus Atom
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posted on 2016-09-29, 13:26 authored by Yuuki Maekawa, Toshifumi Maruyama, Toshiaki MuraiSequential
deprotonation and alkylation of 1,1′-binaphthyloxy-substituted
phosphonoselenoates and phosphonates resulted in the diastereoselective
formation of chiral tri- and tetrasubstituted carbon centers adjacent
to a phosphorus atom.
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Phosphorus Atom Sequential deprotonationTetrasubstituted Carbon Centers AdjacentphosphonoselenoateDeprotonationchiral trialkylationdiastereoselective formationphosphonateChiral Triphosphorus atomBinaphthyloxy-Substituted Phosphonochalcogenoatestetrasubstituted carbon centersbinaphthyloxy-substituted
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