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Self-Assembly Template Driven 3D Inverse Opal Microspheres Functionalized with Catalyst Nanoparticles Enabling a Highly Efficient Chemical Sensing Platform
journal contribution
posted on 2018-01-25, 00:00 authored by Tianshuang Wang, Inci Can, Sufang Zhang, Junming He, Peng Sun, Fangmeng Liu, Geyu LuThe design of semiconductor
metal oxides (SMOs) with well-ordered porous structure has attracted
tremendous attention owing to their larger specific surface area.
Herein, three-dimensional inverse opal In2O3 microspheres (3D-IO In2O3 MSs) were fabricated
through one-step ultrasonic spray pyrolysis (USP) which employed self-assembly
sulfonated polystyrene (S-PS) spheres as a sacrificial template. The
spherical pores observed in the 3D-IO In2O3 MSs
had diameters of about 4 and 80 nm. Subsequently, the catalytic palladium
oxide nanoparticles (PdO NPs) were loaded on 3D-IO In2O3 MSs via a simple impregnation method, and their gas sensing
properties were investigated. In a comparison with pristine 3D-IO
In2O3 MSs, the 3D-IO PdO@In2O3 MSs exhibited a 3.9 times higher response (Rair/Rgas = 50.9) to 100 ppm
acetone at 250 °C and a good acetone selectivity. The detection
limit for acetone could extend down to ppb level. Furthermore, the
3D-IO PdO@In2O3 MSs-based sensor also possess
good long-term stability. The extraordinary sensing performance can
be attributed to the novel 3D periodic porous structure, highly three-dimensional
interconnection, larger specific surface area, size-tunable (meso-
and macroscale) bimodal pores, and PdO NP catalysts.