jo061683p_si_002.cif (19.66 kB)
Rhodium(I)-Catalyzed [2 + 2 + 2] Cycloadditions of Ynamides in the Synthesis of Amide-Substituted Chiral Biaryls
dataset
posted on 2006-10-27, 00:00 authored by Michael R. Tracey, Jossian Oppenheimer, Richard P. HsungRhodium(I)-catalyzed [2 + 2 + 2] cycloadditions of sterically encumbered aryl-substituted ynamides with various
diynes are described here. These cycloadditions provide the
synthesis of an array of new chiral amide-substituted biaryls
that can be useful in future chiral ligand designs.