ol7b03663_si_001.pdf (3.78 MB)
Rhodium-Catalyzed Homocoupling of γ‑Alkylated tert-Propargylic Alcohols
journal contribution
posted on 2017-12-20, 17:19 authored by Xiaowei Dou, Na Liu, Jian Yao, Tao LuAn
unprecedented rhodium-catalyzed homocoupling reaction of γ-alkylated tert-propargylic alcohols is reported, and 2-alkynylated
buta-1,3-diene or 2-alkynylated hexa-1,3,5-triene are generated selectively.
Multiple β-eliminations, including sequential β-carbon,
β-hydrogen, and β-oxygen eliminations from the corresponding
rhodium intermediates, are assumed to be involved during the reaction
process.