ol020051w_si_001.pdf (781.77 kB)
Rh(I)-Catalyzed Intramolecular Allenic Pauson−Khand Reaction: Construction of a Bicyclo[5.3.0]dec-1,7-dien-9-one Skeleton
journal contribution
posted on 2002-04-17, 00:00 authored by Chisato Mukai, Izumi Nomura, Kei Yamanishi, Miyoji Hanaoka1-Phenylsulfonylallenes possessing a hexynyl appendage in refluxing toluene in the presence of catalytic amount of rhodium(I) catalyst under
a carbon monoxide atmosphere underwent regioselective formal [2 + 2 + 1]-cycloaddition to produce the corresponding bicyclo[5.3.0]dec-1,7-dien-9-one derivatives in acceptable yields.