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Rh(III)-Catalyzed Enaminone-Directed C–H Coupling with α‑Diazo-α-phosphonoacetate for Reactivity Discovery: Fluoride-Mediated Dephosphonation for C–C Coupling Reactions
journal contribution
posted on 2018-06-18, 21:20 authored by Chao Song, Chen Yang, Hua Zeng, Wenjing Zhang, Shan Guo, Jin ZhuRh(III)-catalyzed
enaminone-directed C–H coupling with α-diazo-α-phosphonoacetate
has been used for the identification of fluoride-mediated dephosphonation
C–C coupling reactivity for the synthesis of 4-hydroxy-1-naphthoates.
Intermolecular C–C coupling of α-phosphonoacetate and
benzaldehyde for (E)-selective α,β-unsaturated
ester synthesis has also been achieved.