Regulated Crystallization of Efficient and Stable Tin-Based Perovskite Solar Cells via a Self-Sealing Polymer

Tin-based perovskite solar cells (PVSCs) have emerged as the most promising lead-free perovskite materials owing to their superior optoelectronic properties. However, the deficiency of accurate control of the tin-based perovskite crystallization process increases the possibility of unexpected perovskite film morphology and defects, resulting in inferior power conversion efficiency (PCE). Meanwhile, the poor environmental stability of tin-based perovskite films hinders its further development. In this work, a unique polymer [poly­(ethylene-co-vinyl acetate) (EVA)] is introduced into anti-solvent during spin coating of formamidinium tin tri-iodide (FASnI₃) precursor solution. The CO groups contained in EVA have a powerful Lewis acid–base complexation with uncoordinated tin atoms in perovskite grains, which can greatly improve the grain size, optimize the grain orientation, and decrease the surface defects of FASnI₃ films. This strategy offers an impressive PCE of 7.72% with favorable reproducibility. More importantly, the PVSC devices based on FASnI₃–EVA absorbers have a self-encapsulation effect, which exhibits distinguished moisture and oxygen barrier property, thereby retaining 62.4% of the original efficiency value after aging for 48 h in the air with a humidity of 60%. Such a convenient strategy provides a new inspiration for the establishment of stable and high-performance tin-based PVSCs.