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Reactive Catalytic Fast Pyrolysis of Biomass Over Molybdenum Oxide Catalysts: A Parametric Study
journal contribution
posted on 2020-03-25, 14:39 authored by Phillip Cross, Kaige Wang, Joseph Weiner, Elliot Reid, Jonathan Peters, Ofei Mante, David C. DaytonReactive catalytic fast pyrolysis
(RCFP) of biomass with atmospheric
pressure hydrogen is a promising route for the deoxygenation of biomass
pyrolysis vapors while retaining high carbon yields in the bio-crude.
RCFP process development was accomplished in a bench-scale bubbling
fluidized-bed reactor with in situ catalyst configuration. Results
are presented that highlight the impact of temperature, biomass weight
hourly space velocity (WHSV), reaction pressure, and time on stream
on the hydrodeoxygenation of different oxygen-containing species produced
during biomass reactive catalytic fast pyrolysis to improve the bio-crude
product yield and quality. The highest bio-crude and C4+ hydrocarbons yield was 46.5 wt % on a carbon basis. The optimal
temperature range for RCFP is 450–475 °C; the biomass
WHSV should be kept low, around 0.6 h–1 in this
reactor system, to produce a low oxygen content bio-crude (7.2 wt
%), and improvements in the bio-crude yield and quality based on increased
pressure are less significant beyond 2.7 bar. The product composition
varies by at most 10% for up to 3.5 h’ time on stream (biomass-to-catalyst
ratio of 2.6 g g–1), indicating a stable catalyst
activity for hydrodeoxygenation.
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pressure hydrogenMolybdenum Oxide Catalystsbiomass weightbio-crude productParametric Study Reactivereactor systemproduct compositionbiomass WHSVbiomass reactive2.7 barcatalyst activitycarbon basishydrodeoxygenationwtcatalyst configurationtemperature rangebiomass pyrolysis vaporsspace velocityoxygen-containing speciesRCFP process developmentfluidized-bed reactorbiomass-to-catalyst ratioReactive Catalytic Fast Pyrolysiscarbon yields
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