am7b17822_si_001.pdf (3.5 MB)
Rational Design and Development of Lanthanide-Doped NaYF4@CdS–Au–RGO as Quaternary Plasmonic Photocatalysts for Harnessing Visible–Near-Infrared Broadband Spectrum
journal contribution
posted on 2018-04-27, 15:25 authored by Ajay Kumar, Kumbam Lingeshwar Reddy, Suneel Kumar, Ashish Kumar, Vipul Sharma, Venkata KrishnanUtilization of the total solar spectrum
efficiently for photocatalysis has remained a huge challenge for a
long time. However, designing a system by rationally combining nanocomponents
with complementary properties, such as upconversion nanoparticles,
semiconductors, plasmonic metals, and carbonaceous support, offers
a promising route for efficient utilization of solar energy by harnessing
the broadband spectrum. In this work, a series of novel quaternary
plasmonic photocatalysts comprising of lanthanide-doped NaYF4@CdS (UC) core–shell nanostructures decorated with Au nanoparticles
(Au NPs) supported on reduced graphene oxide (RGO) nanosheets were
prepared using the multistep hydrothermal method. The different components
of the prepared nanocomposites could be efficiently employed to utilize
both the visible and near-infrared (NIR) regions. Specifically in
this work, the utility of these quaternary nanocomposites for photocatalytic
degradation of a colorless pharmaceutical pollutant, ciprofloxacin,
under visible and NIR light irradiations has been demonstrated. In
comparison to bare counterparts, our quaternary nanocomposites exhibit
an enhanced photocatalytic activity attributable to the synergistic
effect of different components arranged in such a way that favors
harnessing energy from the broad spectral region and efficient charge
separation. The combination of upconversion and plasmonic properties
along with the advantages of a carbonaceous support can provide new
physical insights for further development of photocatalysts, which
could utilize the broadband spectrum.
History
Usage metrics
Categories
Keywords
nanoparticlemultistep hydrothermal methodQuaternary Plasmonic PhotocatalystsupconversionLanthanide-Doped NaYF 4novel quaternary plasmonic photocatalystsRGOquaternary nanocomposites exhibitNIR light irradiationscomponentUCNPcarbonaceous supportregionlanthanide-doped NaYF 4CdSphotocatalyticbroadband spectrum
Licence
Exports
RefWorks
BibTeX
Ref. manager
Endnote
DataCite
NLM
DC