Poly(isophthalic acid)(ethylene oxide) as a Macromolecular Modulator for Metal–Organic Polyhedra

A new strategy was developed by using a polymer ligand, poly­(isophthalic acid)­(ethylene oxide), to modulate the growth of metal–organic polyhedra (MOP) crystals. This macromolecular modulator can effectively control the crystal habit of several different Cu<sub>24</sub>L<sub>24</sub> (L = isophthalic acid derivatives) MOPs. The polymer also directed the formation of MOP structures under reaction conditions that only produce metal–organic frameworks in the absence of modulator. Moreover, the polymer also enabled the deposition of MOP crystals on glass surfaces. This macromolecular modulator strategy provides an innovative approach to control the morphology and assembly of MOP particles.