ic202769e_si_002.cif (12.55 kB)
Polarized Micropores in a Novel 3D Metal–Organic Framework for Selective Adsorption Properties
dataset
posted on 2012-05-07, 00:00 authored by Chengli Jiao, Jian Zhang, Shuang Wang, Xiaoliang Si, Wansheng You, Zhangpeng Li, Zhonggang Wang, Hao Yu, Zelimir Gabelica, Huai-Ying Zhou, Lixian Sun, Fen XuA novel 3D porous metal–organic framework with
1D polarized
channels was synthesized, and its adsorption properties for gas separation
and chemical sensing were studied. The framework shows a preferential
adsorption of CO2 over N2 with a selectivity
of 22:1. It also exhibits a very good sensitivity to water with respect
to most of the organic solvents in view of chemical sensing applications.
