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Physico-Geometrical Kinetics of Solid-State Reactions in an Undergraduate Thermal Analysis Laboratory
journal contribution
posted on 2014-02-11, 00:00 authored by Nobuyoshi Koga, Yuri Goshi, Masahiro Yoshikawa, Tomoyuki TatsuokaAn undergraduate kinetic experiment
of the thermal decomposition
of solids by microscopic observation and thermal analysis was developed
by investigating a suitable reaction, applicable techniques of thermal
analysis and microscopic observation, and a reliable kinetic calculation
method. The thermal decomposition of sodium hydrogen carbonate is
selected as the suitable reaction for the student experiments, because
its physico-geometrical reaction mechanism is approximately described
by the two-dimensional phase boundary controlled model, and its reaction
kinetics are less sensitive to the measurement conditions of thermal
analyses. On the basis of simple microscopic observations of this
reaction, development of the physico-geometrical reaction model and
derivation of the kinetic model function are imposed on students.
The kinetic analysis is also performed using the kinetic rate data
recorded by a single thermogravimetric run under modulated temperature
conditions. This reduces the time spent in the laboratory and enables
the application of a two-step kinetic calculation that provides reliable
kinetic results. From the results, students can interpret the kinetics,
which are closely related to the physico-geometrical characteristics
of the reaction. A one-day undergraduate course in a thermal analysis
laboratory is proposed from research and trials conducted in our university.
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Keywords
model functionstudent experimentsAnalysis LaboratoryPhysico-Geometrical KineticsSolid-State Reactionsreaction kineticstemperature conditionscalculation methodphysico-geometrical characteristicsanalysis laboratoryrate dataphase boundarysodium hydrogen carbonatemeasurement conditionsphysico-geometrical reaction mechanismphysico-geometrical reaction model
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