Pd(II)-Catalyzed Intermolecular 1,2-Diamination of Conjugated Dienes

Bar, Grégory L. J.; Lloyd-Jones, Guy C.; Booker-Milburn, Kevin I.

doi:10.1021/ja051181d.s002

ja051181d_si_002.pdf (20.72 kB)

Pd(II)-Catalyzed Intermolecular 1,2-Diamination of Conjugated Dienes

journal contribution

posted on 2005-05-25, 00:00 authored by Grégory L. J. Bar, Guy C. Lloyd-Jones, Kevin I. Booker-Milburn

A Pd(II) chloride precatalyst, in the presence of 1 equiv of benzoquinone, effects highly efficient, regioselective 1,2-diamination of 1,3-dienes using dialkyl ureas under mild conditions. There is no requirement for a large excess of diene.

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requirement presence Conjugated Dienes diene Pd benzoquinone regioselective precatalyst chloride dialkyl ureas Diamination 1 equiv Intermolecular diamination

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Pd(II)-Catalyzed Intermolecular 1,2-Diamination of Conjugated Dienes

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