Palladium-Catalyzed Selective Acyloxylation Using Sodium Perborate as Oxidant
2011-03-04T00:00:00Z (GMT) by
Sodium perborate (SPB), a principal component of washing powders, was employed as an inexpensive and eco-friendly oxidant in the palladium-catalyzed C−H acyloxylation of alkenes in excellent regio- and stereochemistry. The reactions used anhydrides as acyloxy sources. The method applies to both terminal and internal alkenes, and even benzylic C−H oxidation.