posted on 2020-03-23, 11:34authored byJiafeng Jin, Jinsheng Sun, Kaihe Lv, Xuan Guo, Jia Liu, Yingrui Bai, Xianbin Huang, Jingping Liu, Jintang Wang
The ever-mounting drilling operations
in the petroleum industry
have been accompanied by a tremendous amount of wasted drilling fluid,
polycyclic aromatic hydrocarbons (PAHs), which poses a huge threat
to human health and the ecosystem. In this study, a novel oxygen-rich
defective photocatalyst with multiheterostructure was fabricated by
a two-step deposition, which exhibits impressive photocatalytic activity
toward naphthalene and pyrene under full-spectrum irradiation. Fourier
transform infrared spectroscopy, Raman shift, and X-ray diffraction
analysis were employed to verify the functional group interaction
and modification mechanism. The morphology and microstructure of the
synthesized composite were investigated using scanning electron microscopy
with X-ray mapping system and transmission electron microscopy. Compared
with BiO2–x or Ag3PO4 alone, the narrow bandgap of BiO2–x/Ag3PO4/CNT composite could promote the
photocatalytic efficiency via enhancing its optical absorption capacity,
which was confirmed by the result of UV–vis–NIR diffuse
reflection spectra. Prepared BiO2–x/Ag3PO4/CNT composite could remove up to 90%
of naphthalene after irradiating for 15 min with visible and near-infrared
light. Furthermore, a potential mechanism between the synergy of the
photocatalysts was revealed according to the results of the ESR spectra
and photoelectrochemical test. This study offers a novel photocatalyst
for PAHs removal from wasted drilling fluids by harvesting the full
spectrum of solar light.