One-Pot Synthesis of Benzo[1,4]thiazin-3(4H)‑ones and a Theoretical Study of the S–N
Type Smiles Rearrangement Mechanism

Zhao, Yongmei; Wu, Yanmiao; Jia, Jiong; Zhang, Dongju; Ma, Chen

doi:10.1021/jo3014287.s002

jo3014287_si_002.pdf (1.28 MB)

One-Pot Synthesis of Benzo[1,4]thiazin-3(4H)‑ones and a Theoretical Study of the S–N Type Smiles Rearrangement Mechanism

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posted on 2012-10-05, 00:00 authored by Yongmei Zhao, Yanmiao Wu, Jiong Jia, Dongju Zhang, Chen Ma

Benzo[1,4]thiazin-3(4H)-one derivatives are conveniently prepared in one pot via a Smiles rearrangement (SR) tandem reaction. In order to understand the reaction, we present here a theoretical study on the S–N type SR mechanism.

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Keywords

Type mechanism derivative type Synthesi Theoretical Study MechanismBenzo tandem reaction Rearrangement Smiles rearrangement Benzo SR

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